Investigations of the chemiluminescent reactions of electrogenerated species (ecl) are summarized in the final technical report. We have become interested in polymer electrodes and in the possibility of studying electron-transfer reactions and ion transport in polymers by utilizing ecl techniques. We have recently reported the ecl of Ru(bpy)3 (2+) (bpy=2,2'-bipyridine) incorporated into a Nafion polymer film on an electrode surface. The electrochemical behavior and ecl of Ru(bpz) 2; (bpz-3(2+) (bpz=2,2'-bipyrazine) in acetonitrile solution have been investigated. Luminescence at Semiconductor Electrodes and Colloidal Dispersions are reported. Photoluminescence (pl) and photoinduced oxygen adsorption of colloidal zinc sulfide dispersions have been studied. Pl and electroluminescence (el) on ZnS single crystals and polycrystals doped with different impurities have been studied in various media (air, aqueous or nonaqueous solutions containing various redox couples).

plus-circle Add Review

comment

Reviews